INCORPORATION OF ALKALINE-EARTH METALS Ca, Mg, Ba and Sr IN MCM-41 FOR APPLICATION AS CO2 ADSORVENTS IN THE PRE-SALES NATURAL GAS CURRENTS
DOI:
https://doi.org/10.18540/jcecvl5iss2pp0148-0152Palavras-chave:
Adsorption, Impregnation, MCM-41Resumo
The new oil fields discovered in the Pre-Salt Province have large oil reserves, but the technological challenges for their economic exploitation are enormous. One of the problems with these reservoirs is that the associated gas has high concentrations of carbon dioxide, which must be removed and disposed of properly. In this way it is necessary to develop technologies for the separation of CO2 from natural gas streams, but there is a complication for these new technologies; the fact that they must be able to treat currents with relatively high concentrations of carbon dioxide. In the present project, the alkaline-earth cations Ca, Mg, Ba and Sr in the molecular sieve MCM-41 will be impregnated for adsorption in natural gas streams, as this modification will provide the formation of acid sites favoring the adsorption reaction.Downloads
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Referências
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CHENG, Z. H., YASUKAWA, A., KANDORI, K., ISHIKAWA, T. FTIR Study of Adsorption of CO2 on Nonstoichiometric Calcium Hydroxyapatite. Langmuir, Osaka, Japan, v. 14, p. 6681-6686, 1998.
CHAUDHARI, K., BAL, R., CHANDWADKAR, A. J., SIVASANKER, S. Beckmann rearrange-ment of cyclohexanone oxime over mesoporous Si-MCM-41 and Al-MCM-41 molecular sieves. Journal of Molecular Catalysis A: Chemical, Maharashtra, India, v. 177, p. 247-253, 2002.
ESWARAMOORTHI, I.; SUNDARAMURTHY, V.; LINGAPPAN, N. Hydroisomerisation of C6-C7 n-alkanes Pt loaded zirconium containing Al-MCM-41 molecular sieves. Microporous And Mesoporous Materials, Chennai, India, v.71, p.109-115, 2004.
MARLER, B.; OBERHAGEMANN, U.; VOLTMANN, S.; GIES, H. Influence of the sorbate type on the XRD peak intensities of loaded MCM-41. Microporous materials, Bochum, Germany, v.6, p.375-383, 1996.
ORR JR, F. M. Storage of Carbon Dioxide in Geologic Formations. Journal of Petroleum Technology, California, United States, v. 56, p. 90-97. 2004.
QUINTELLA, S.A. Síntese, caracterização e propriedades catalíticas da peneira molecular nanoestruturada modificada com latânio. 2009. 88f. Tese (Doutorado em Engenharia Química) - Universidade Federal do Rio Grande do Norte, Natal, RN, 2009.
SAYARI, A. Periodic mesoporous materials: synthesis, characterization and potencial applications. Studies in Surface Science Catalysis, Quebec, Canadá, v. 102, p. 1-46, 1996.
SAMANTA, A.; ZHAO, A.; SHIMIZU, G. K. H.;SARKAR, P.; GUPTA, R. Post-combustion CO2 capture using solid sorbents: A review. Ind. & Eng.Chem. Res., Alberta, Canada, v.51, p. 1438-1463, 2012.
STRAZISAR, BRIAN R.; ANDERSON. RICHARD R., WHITE. CURT M. Degradation of monoethanolamine used in carbon dioxide capture from flue gas of a coal-fired electric power generating station. National Energy Technology Laboratory clean air Technology Division, Pittsburgh, Pennsylvania, v. 47, pp 15236, 2000.
WANG, X.; MA, X.; SCHWARTZ, V.; CLARK. J. C.; OVERBURY, S. H.; ZHAO, S.; XU, X.; SONG, C. A solid molecular basket sorbent for CO2 capture from gas streams with low CO2 concentration under ambient conditions. Physical Chemistry Chemical Physics, Pennsylvania, United States, v. 14, p. 1485, 2011.
ZHAO, B.; SU, Y.; TAO, W.; LI, L.; PENG, Y. Post-combustion CO2 capture by aqueous ammonia: A state-of-the-art review. International Journal of Greenhouse Gas Control, Shanghai, China, v. 9, p. 355-371, 2012.
CADIGAN. C. A; CORPUZ A. R.; LIN F.; CASKEY C. M.; FINCH K. B. H; RICHARDS X. W; RICHARDS R. M. Nanoscale (111) faceted rock-salt metal oxides in catalysis. Catal. Sci. Technol., Colorado, United States, v. 3, p. 900-911, 2013.
CHENG, Z. H., YASUKAWA, A., KANDORI, K., ISHIKAWA, T. FTIR Study of Adsorption of CO2 on Nonstoichiometric Calcium Hydroxyapatite. Langmuir, Osaka, Japan, v. 14, p. 6681-6686, 1998.
CHAUDHARI, K., BAL, R., CHANDWADKAR, A. J., SIVASANKER, S. Beckmann rearrange-ment of cyclohexanone oxime over mesoporous Si-MCM-41 and Al-MCM-41 molecular sieves. Journal of Molecular Catalysis A: Chemical, Maharashtra, India, v. 177, p. 247-253, 2002.
ESWARAMOORTHI, I.; SUNDARAMURTHY, V.; LINGAPPAN, N. Hydroisomerisation of C6-C7 n-alkanes Pt loaded zirconium containing Al-MCM-41 molecular sieves. Microporous And Mesoporous Materials, Chennai, India, v.71, p.109-115, 2004.
MARLER, B.; OBERHAGEMANN, U.; VOLTMANN, S.; GIES, H. Influence of the sorbate type on the XRD peak intensities of loaded MCM-41. Microporous materials, Bochum, Germany, v.6, p.375-383, 1996.
ORR JR, F. M. Storage of Carbon Dioxide in Geologic Formations. Journal of Petroleum Technology, California, United States, v. 56, p. 90-97. 2004.
QUINTELLA, S.A. Síntese, caracterização e propriedades catalíticas da peneira molecular nanoestruturada modificada com latânio. 2009. 88f. Tese (Doutorado em Engenharia Química) - Universidade Federal do Rio Grande do Norte, Natal, RN, 2009.
SAYARI, A. Periodic mesoporous materials: synthesis, characterization and potencial applications. Studies in Surface Science Catalysis, Quebec, Canadá, v. 102, p. 1-46, 1996.
SAMANTA, A.; ZHAO, A.; SHIMIZU, G. K. H.;SARKAR, P.; GUPTA, R. Post-combustion CO2 capture using solid sorbents: A review. Ind. & Eng.Chem. Res., Alberta, Canada, v.51, p. 1438-1463, 2012.
STRAZISAR, BRIAN R.; ANDERSON. RICHARD R., WHITE. CURT M. Degradation of monoethanolamine used in carbon dioxide capture from flue gas of a coal-fired electric power generating station. National Energy Technology Laboratory clean air Technology Division, Pittsburgh, Pennsylvania, v. 47, pp 15236, 2000.
WANG, X.; MA, X.; SCHWARTZ, V.; CLARK. J. C.; OVERBURY, S. H.; ZHAO, S.; XU, X.; SONG, C. A solid molecular basket sorbent for CO2 capture from gas streams with low CO2 concentration under ambient conditions. Physical Chemistry Chemical Physics, Pennsylvania, United States, v. 14, p. 1485, 2011.
ZHAO, B.; SU, Y.; TAO, W.; LI, L.; PENG, Y. Post-combustion CO2 capture by aqueous ammonia: A state-of-the-art review. International Journal of Greenhouse Gas Control, Shanghai, China, v. 9, p. 355-371, 2012.
CADIGAN. C. A; CORPUZ A. R.; LIN F.; CASKEY C. M.; FINCH K. B. H; RICHARDS X. W; RICHARDS R. M. Nanoscale (111) faceted rock-salt metal oxides in catalysis. Catal. Sci. Technol., Colorado, United States, v. 3, p. 900-911, 2013.
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Publicado
2019-04-26
Como Citar
Silva Ribeiro, T. R., de Melo Silva, D. C., Pereira Martins da Costa, T., & Sousa da Silva, A. O. (2019). INCORPORATION OF ALKALINE-EARTH METALS Ca, Mg, Ba and Sr IN MCM-41 FOR APPLICATION AS CO2 ADSORVENTS IN THE PRE-SALES NATURAL GAS CURRENTS. The Journal of Engineering and Exact Sciences, 5(2), 0148–0152. https://doi.org/10.18540/jcecvl5iss2pp0148-0152
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Seção
Engineering of Petroleum, Natural Gas and Biofuels