STUDY OF BIODIESEL PRODUCTION BY HETEROGENEOUS CATALYSIS USING MAGNETIC NANOPARTICLES SUPPORTED IN SILICA IN A PACKED BED REACTOR

Allan Boury; Andeson Zussa; Christian Campos; Marta Felix; Mariana Felix; Maristhela Marin; Luis Ferreira; Newton Ferreira; Sergio Toma; Marcos Toyama

doi:10.18540/jcecvl5iss1pp0137-0142

Auteurs

Allan Boury Centro Universitário da FEI
Andeson Zussa
Christian Campos
Marta Felix
Mariana Felix
Maristhela Marin
Luis Ferreira
Newton Ferreira
Sergio Toma
Marcos Toyama

DOI :

https://doi.org/10.18540/jcecvl5iss1pp0137-0142

Mots-clés :

Packed Bed Reactor, Nanoparticle, silica, Transesterification

Résumé

In this work the biodiesel production was studied through heterogeneous catalysis using SPIONs in silica. The reaction was conducted in a fixed bed reactor immersed in thermostated bath to maintain the temperature at 60 °C using 1:6:5 (soybean/methanol/tert-butanol) molar ratios between reagents and reaction times of 6,8 and 10 hours. The reactions were also conducted in Erlenmeyer incubators at Shaker under the same conditions of molar ratios and temperature, with agitation of 300 rpm, samples being withdrawn from time to time ranging from 0.25 to 8 hours. The results showed that when the reaction was conducted in a fixed bed reactor the best conversion was achieved in batch of 10 hours being equal to 3.18% and that when incubated in Shaker a conversion of 36.04% in 8 hours. In this study the kinetic constant was also determined from the experiments incubated at Shaker and proposed a transesterification process model using the ASPEN PLUS (R) process simulator.

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Biographie de l'auteur

Allan Boury, Centro Universitário da FEI

Possui graduação em Engenharia Química pela Universidade Estadual do Oeste do Paraná – UNIOESTE (2003); Mestrado em Engenharia Química na área de desenvolvimento de processos químicos pela Universidade Estadual de Campinas DPQ/FEQ/UNICAMP (2007); Capacitação em Gerenciamento de Projetos pela Universidade Estadual de Campinas – UNICAMP (2008) e Doutorado em Engenharia Química pela Faculdade de Engenharia Química da Universidade Estadual de Campinas – UNICAMP (2012). Atuou de 2012 a 2014 como pesquisador colaborador no LCAP: Laboratório de Controle e Automação de Processos, DESQ/FEQ/UNICAMP e de 2014 a 2015 como Professor Doutor I MS3.1 na Faculdade de Engenharia de Alimentos da UNICAMP. Atualmente é Professor Adjunto I no Centro Universitário da FEI e pesquisador colaborador no LCAP/ DESQ/FEQ/UNICAMP. Tem experiência na área de Engenharia Química, com ênfase em Reatores Poliméricos, Modelagem e Simulação e Controle e Automação, atuando principalmente nos seguintes temas: polimerização via radical livre controlado, RAFT, Comunicação OPC, CLP, refrigeração industrial, IA (lógica fuzzy e neuro-fuzzy e redes neurais), Identificação de Sistemas, Controle e instrumentação.

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